Guide
for an Instructor
- Review the tutorial material and do the
Exercises.
- We would appreciate comments on the tutorial
material and its potential use in teaching.
- Direct your attention to the Resource
section of this site.
- We would appreciate comments on this material,
as well as additional material that you think would be appropriate
(in particular, any papers of your own on this subject). Please
contact W.
R. Smith.
It may be convenient to download the entire
tutorial file (in Adobe .pdf format) and at your convenience,
work through the steps that do not require use of the Java applet;
then come back to the site to use the applet. An item part-way
down the tutorial menu bar allows you to do download this file.
Also, be sure to read the page outlining the Technical
Requirements for Using this Site.
Some Personal
Thoughts on the Pedagogy of Chemical Reaction Stoichiometry (CRS):
- We believe that CRS should be studied
in its own right, "uncontaminated" by any implications
arising from reaction networks, mechanisms, and pathways, or
from reaction equilibrium. This is in order to understand the
foundations of CRS so that it may play a role as a servant to
these other matters, which transcend CRS.
- We believe that, in the pedagogy of chemistry,
there is an over-emphasis on systems that can be represented
by a single chemical equation (R=1, corresponding to a
single chemical reaction) in the context of "balancing a
given reaction" using additional artifices and "tricks."
Important as this case is, if the pedagogy does not go beyond
this stage, even in elementary teaching, the danger exists of
creating uncertainty (or confusion or ignorance) in the mind
of a student as to the greater role of CRS in chemistry, and
how to identify and treat systems for which more than one equation
is required. In the exercises in this tutorial, we give examples
of this "confusion" as it exists in the literature.
- We believe that, even for the case
R=1, the artifices and tricks can be quite involved, as evidenced
by the large number of papers published on this subject (most
of which are along the lines of "my trick is better than
yours"). We believe that there are two drawbacks to these
approaches: (1) the complex approach required for some problems
can lead to an overemphasis on the artifices and tricks themselves,
rather than on the underlying chemistry; (2) this approach is
inherently incapable of establishing the correct value of R.
We believe that all of these artifices are unnecessary
in CRS.
- We believe that it is desirable to develop
the pedagogy of CRS based on simple concepts with which the student
is already familiar: (1) atomic and charge conservation; (2)
molecular formulas; and (3) methods for solving linear algebraic
equations. The MRM ("Matrix Reduction Method" described
in the tutorial uses only these concepts.
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